• 文献标题:   Flexible Free-Standing Graphene/SnO2 Nanocomposites Paper for Li-Ion Battery
  • 文献类型:   Article
  • 作  者:   LIANG JF, ZHAO Y, GUO L, LI LD
  • 作者关键词:   flexible, freestanding, gsp, liion battery, cycling stability, capacity
  • 出版物名称:   ACS APPLIED MATERIALS INTERFACES
  • ISSN:   1944-8244 EI 1944-8252
  • 通讯作者地址:   Beihang Univ
  • 被引频次:   111
  • DOI:   10.1021/am301962d
  • 出版年:   2012

▎ 摘  要

A flexible free-standing graphene/SnO2 nanocomposites paper (GSP) was prepared by coupling a simple filtration method and a thermal reduction together for the first time. Compared with the pure SnO2 nanoparticles, the GSP exhibited a better cycling stability, because the graphene with high mechanical strength and elasticity can work as a buffer to prevent the volume expansion and contraction of SnO2 nanoparticles during the Li+ insertion/extraction process. Meanwhile, compared with single graphene paper, the GSP showed a higher capacity because of the hybridizing with higher capacity SnO2 nanoparticles. The excellent electrochemical performance of the GSP as an anode material in Li-ion battery was obtained. The as-prepared GSP shows a great potential for flexible Li-ion batteries.