• 文献标题:   Wrapping Graphene Sheets Around Organic Wires for Making Memory Devices
  • 文献类型:   Article
  • 作  者:   WANG SA, MANGA KK, ZHAO M, BAO QL, LOH KP
  • 作者关键词:  
  • 出版物名称:   SMALL
  • ISSN:   1613-6810 EI 1613-6829
  • 通讯作者地址:   Natl Univ Singapore
  • 被引频次:   14
  • DOI:   10.1002/smll.201100426
  • 出版年:   2011

▎ 摘  要

Hybrids of organic semiconductors and graphene can generate a whole new class of materials with enhanced properties. A simple solution-phase route to synthesize a hybrid material made of organic nanowires and graphene oxide (GO) sheets is demonstrated by sonicating tetracene molecules and GO together in diluted fuming nitric acid. The self-assembled tetracene-derived organic wires become encapsulated by GO sheets during the reaction to produce an interconnected, one-dimensional/two-dimensional lamellar film. Memory devices fabricated using the hybrid film as the sandwiched layer between aluminum electrodes exhibit excellent electrical bistability. The charge retention properties are attributed to charge transfer and a charge-trapping/detrapping mechanism operational at the interfaces and isolated matrices of the GO-tetracene hybrid.