• 文献标题:   Fluoro-functionalized graphene oxide/polyaniline composite electrode material for supercapacitors
  • 文献类型:   Article
  • 作  者:   LI YN, XING RG, ZHANG BW, BULIN C
  • 作者关键词:   fluorofunctionalized graphene oxide, polyaniline, supercapacitor, specific capacitance
  • 出版物名称:   POLYMERS POLYMER COMPOSITES
  • ISSN:   0967-3911 EI 1478-2391
  • 通讯作者地址:   Inner Mongolia Univ Sci Technol
  • 被引频次:   2
  • DOI:   10.1177/0967391118817404
  • 出版年:   2019

▎ 摘  要

A novel high-performance electrode material based on fluoro-functionalized graphene oxide (GOF)/polyaniline (PANI) composites was synthesized via in situ polymerization of monomer in the presence of GOF. The composite was characterized by Fourier transform infrared spectrometry, X-ray diffraction (XRD), and the field emission scanning electron micrographs. The electrochemical properties of the composites were measured based on cyclic voltammetry, galvanostatic charge/discharge, and AC impedance spectroscopy. When the obtained composites with a mass ratio is 3% GOF/PANI, the results showed that GOF as a support material provides additional electron transfer paths, as well as active sites, for the electrochemical redox reaction of PANI, which helps to increase its pseudocapacitance. A specific capacitance of 502 F.g(-1) was obtained at a current density of 1.0 A.g(-1) in I mol.L-1 H2SO4, as well as excellent cycling stability with 95% of its initial capacitance after 600 cycles. These encouraging results illustrate the exciting potential for high-performance, electrical energy storage devices based on this new class of carbon material.