• 文献标题:   Melamine-functionalized graphene oxide: Synthesis, characterization and considering as pseudocapacitor electrode material with intermixed POAP polymer
  • 文献类型:   Article
  • 作  者:   AJDARI FB, KOWSARI E, EHSANI A, CHEPYGA L, SCHIROWSKI M, JAGER S, KASIAN O, HAUKE F, AMERI T
  • 作者关键词:   synthesi, functionalized graphene oxide, supercapacitor, characterization
  • 出版物名称:   APPLIED SURFACE SCIENCE
  • ISSN:   0169-4332 EI 1873-5584
  • 通讯作者地址:   Friedrich Alexander Univ Erlangen Nuremberg
  • 被引频次:   11
  • DOI:   10.1016/j.apsusc.2018.07.215
  • 出版年:   2018

▎ 摘  要

In this study, Melamine functionalized graphene oxide (FGO-Melamine) was synthesized by chemical route. The prepared functionalized graphene oxide was characterized by different analytical techniques such as FT-IR, Raman spectroscopy, thermogravimetry coupled with mass spectrometry (TG-MS), X-Ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM), and X-ray photoelectron spectroscopy (XPS). To improve electrochemical properties of polyorthoaminophenol (POAP), the electropolymerized POAP/FGO-Melamine films, employed as an active electrode regarding electrochemical performance. In terms of electrochemical measurements, galvanostatic charge-discharge evaluation, EIS (electrochemical impedance spectroscopy) and CV (cyclic voltammetry) were employed for conducing an enquiry into supercapacitive performance of nanocomposite of POAP/FGO-Melamine. This graphene-based electrode showed a specific capacitance (SC) by 273 F g(-1) and high energy of 37.91 W kg(-1) at power density of 500 W kg(-1). The novel materials synthesized in the current work show higher efficiency compared to the carbon-based ones concerning redox reactions of capacitors consisting of good stability in the existence of aqueous electrolyte, large active surface area and ease synthesis method.