• 文献标题:   Mechanistic study of the visible-light-driven photocatalytic inactivation of bacteria by graphene oxide-zinc oxide composite
  • 文献类型:   Article, Proceedings Paper
  • 作  者:   WU D, AN TC, LI GY, WANG W, CAI YC, YIP HY, ZHAO HJ, WONG PK
  • 作者关键词:   visible light driven photocatalyst, graphene oxidezinc oxide composite, bacterial inactivation, photosensitizing mechanism
  • 出版物名称:   APPLIED SURFACE SCIENCE
  • ISSN:   0169-4332 EI 1873-5584
  • 通讯作者地址:   Chinese Acad Sci
  • 被引频次:   19
  • DOI:   10.1016/j.apsusc.2015.08.033
  • 出版年:   2015

▎ 摘  要

The visible-light-driven (VLD) photocatalytic activity of graphene oxide-zinc oxide (GO-ZnO) composite prepared by a simple hydrothermal method was evaluated toward the inactivation of Escherichia coli K-12. The results showed that GO-ZnO composite had excellent VLD photocatalytic bacterial inactivation activity, comparing with those of ZnO and GO, which was attributed to the strong interaction between ZnO and GO in the composite. Accordingly, an interaction induced VLD photocatalytic inactivation mechanism of the strong interaction of GO with ZnO within the GO-ZnO composite was proposed. GO served as a photosensitizer and facilitated the charge separation and transfer, thus boosted the massive production of reactive oxygen species such as center dot OHbulk, which was identified as the major reactive species from conduction band of ZnO, and resulted in a remarkable enhancement of bacterial inactivation efficiency. Moreover, GO-ZnO composite showed obviously superior photocatalytic bacterial inactivation within 10 min under natural solar light irradiation, indicating that GO-ZnO composite has great potential in wastewater treatment and environmental protection. (C) 2015 Elsevier B.V. All rights reserved.