• 文献标题:   Utilization of Rice Husk Ash in the Preparation of Graphene-Oxide-Based Mesoporous Nanocomposites with Excellent Adsorption Performance
  • 文献类型:   Article
  • 作  者:   LIOU TH, LIOU YH
  • 作者关键词:   rice husk ash, graphene oxide, sba15, nanocomposite, sustainable utilization
  • 出版物名称:   MATERIALS
  • ISSN:  
  • 通讯作者地址:  
  • 被引频次:   13
  • DOI:   10.3390/ma14051214
  • 出版年:   2021

▎ 摘  要

Rice husk is an agricultural biomass waste. Burning rice husks in an oxygenic atmosphere releases thermal energy and produces ash that is rich in silica. Rice husk ash (RHA) can be used as a sustainable source of silica for producing high-value-added products. In this study, mesostructural graphene oxide (GO)/SBA-15, a graphene-based hybrid material, was synthesized from RHA. The materials are inspected by Fourier transform infrared spectrometer, Raman spectrometer, field-emission scanning electron microscopy, transmission electron microscopy, surface area analyzer, and X-ray diffraction analyzer. Studies have revealed that GO/SBA-15 possesses various oxygen functional groups that are helpful for dye adsorption. The material consisted of high pore volume of 0.901 cm(3)/g, wide pores of diameter 11.67 nm, and high surface area of 499 m(2)/g. Analysis of the methylene blue (MB) adsorption behavior of GO/SBA-15 composites revealed that their adsorption capacity depended on the gelation pH, GO content, adsorbent dosage, and initial dye (MB) concentration. The highest adsorption capacity of GO/SBA-15 was 632.9 mg/g. Furthermore, the adsorption isotherms and kinetics of GO/SBA-15 were investigated. This study demonstrated the great advantage of treated RHA and the potential of this material for use in organic dye adsorption.