• 文献标题:   Nanozyme Sensor Arrays Based on Heteroatom-Doped Graphene for Detecting Pesticides
  • 文献类型:   Article
  • 作  者:   ZHU YY, WU JJX, HAN LJ, WANG XY, LI W, GUO HC, WEI H
  • 作者关键词:  
  • 出版物名称:   ANALYTICAL CHEMISTRY
  • ISSN:   0003-2700 EI 1520-6882
  • 通讯作者地址:   China Agr Univ
  • 被引频次:   5
  • DOI:   10.1021/acs.analchem.9b05110
  • 出版年:   2020

▎ 摘  要

Pesticides, widely used for pest control and plant growth regulation, have posed a threat to the environment and human health. Conventional methods to analyze pesticide residues are not applied to resource-limited areas because of their high cost, complexity, and requirements for expensive instruments (such as GC/MS and LC/MS). To address these challenges, herein we fabricated colorimetric nanozyme sensor arrays based on heteroatom-doped graphene for detection of aromatic pesticides. The active sites of nanozymes could be differentially masked when different pesticides were adsorbed on the graphene, which in turn resulted in the decrease of their peroxidase-mimicking activities. On the basis of this principle, five pesticides (i.e., lactofen, fluoroxypyr-meptyl, bensulfuron-methyl, fomesafen, and diafenthiuron) from 5 to 500 mu M were successfully discriminated by the sensor arrays. In addition, discrimination for different concentrations of each pesticide and different ratios of two mixed pesticides were also demonstrated. The practical application of the sensor arrays was further validated by successfully discriminating the pesticides in soil samples. This work not only provides a facile and cost-effective method to detect pesticides but also makes a positive contribution to food safety and environmental protection.