• 文献标题:   Flow-induced ordering of particles and flow velocity profile transition in a tube flow of graphene oxide dispersions
  • 文献类型:   Article
  • 作  者:   HONG SH, SHEN TZ, SONG JK
  • 作者关键词:   lyotropic, flowinduced ordering, graphene oxide dispersion
  • 出版物名称:   LIQUID CRYSTALS
  • ISSN:   0267-8292 EI 1366-5855
  • 通讯作者地址:   Sungkyunkwan Univ
  • 被引频次:   13
  • DOI:   10.1080/02678292.2014.984355
  • 出版年:   2015

▎ 摘  要

We measured the S- and P-order parameters of flow-induced ordered graphene oxide (GO) particles and the flow velocity profiles for a flowing aqueous GO dispersion in a tube, by using an optical method. The order parameters clearly exhibit increasing concentric biaxial ordering as the flow velocity increases, with the exception of a disordered centre. Newtonian to non-Newtonian transition in the flow velocity profile is found, changing from a parabolic shape to a fuller shape at very low Reynolds numbers less than 10. This is attributed to the shear thinning effect (i.e., an ordering-induced reduction in viscosity). In the Newtonian flow, a uniaxial ordering was dominant; whereas a biaxial ordering sharply increased in the non-Newtonian flow, indicating that both the ordering of GO particles and the interparticle interactions influence the flow profile transition.