• 文献标题:   Dynamic mechanical properties, thermal and heat resistance of multiblock co-poly(urethane-imide) films with graphene and tungsten disulfide
  • 文献类型:   Article
  • 作  者:   DIDENKO AL, SMIRNOVA VE, POPOVA EN, VAGANOV GV, KUZNETCOV DA, SVETLICHNYI VM, TOLOCHKO OV, VASILYEVA ES, YUDIN VE, KUDRYAVTSEV VV
  • 作者关键词:   copoly urethaneimide, multiblock block copolymer, nanoparticle, tungsten disulfide, graphene, tga, dsc, dma, heat resistance, rubberlike high elasticity, thermoplastic elastomer
  • 出版物名称:   RUSSIAN CHEMICAL BULLETIN
  • ISSN:   1066-5285 EI 1573-9171
  • 通讯作者地址:   Russian Acad Sci
  • 被引频次:   4
  • DOI:   10.1007/s11172-019-2599-8
  • 出版年:   2019

▎ 摘  要

Organic-inorganic composites filled with nanoscale graphene and tungsten disulfide particles using thermoelastoplastic multiblock co-poly(urethane-imide)s as polymer matrices were obtained. The matrix polymers were the products of the polycondensation of 1,3-bis-(3 ',4-dicarboxyphenoxy)benzene dianhydride, 1,4-bis(aminophenoxy)diphenyl sulfone, and two aliphatic polyesters terminated by 2,4-toluene diisocyanate, namely, polypropylene glycol (M-n = 2300) and poly(ethylene adipate) (M-n = 2700). The weight fraction of aromatic segments in samples of co-poly(urethane-imide)s differed by a factor of two. Obtained composites were investigated by TGA, DSC, and DMA methods.