• 文献标题:   One-pot solvothermal synthesis of graphene-supported TiO2 (B) nanosheets with enhanced lithium storage properties
  • 文献类型:   Article
  • 作  者:   ZHANG Z, CHU QX, LI HY, HAO JH, YANG WS, LU BP, KE X, LI J, TANG JL
  • 作者关键词:   graphene, tio2 b nanosheet, nanosheetsonnanosheet, lithium ion batterie
  • 出版物名称:   JOURNAL OF COLLOID INTERFACE SCIENCE
  • ISSN:   0021-9797 EI 1095-7103
  • 通讯作者地址:   Jilin Univ
  • 被引频次:   15
  • DOI:   10.1016/j.jcis.2013.07.053
  • 出版年:   2013

▎ 摘  要

A facile process was developed for the synthesis of graphene-supported TiO2 (B) nanosheets (GTBN) composite based on the hydrothermal treatment titanium (III) chloride and graphene oxide in an ethylene glycol. The morphology and microstructure of the composites were examined by X-ray diffraction, Xray photoelectron spectroscopy, transmission electron microscopy, and Raman spectroscopy. The obtained GTBN show a high thermal stability and the phase transformation of TiO2 (B) to anatase can be prevented by graphene after pyrolysis of GTBN at 350 degrees C for 2 h. Furthermore, GTBN exhibited high rate performance and stability of lithium ion batteries, due to the enhanced conductivity of the electrode and accommodation to volume/strain changes during lithium insertion-extraction. (C) 2013 Elsevier Inc. All rights reserved.