• 文献标题:   Controllable Formation of Niobium Nitride/Nitrogen-Doped Graphene Nanocomposites as Anode Materials for Lithium-Ion Capacitors
  • 文献类型:   Article
  • 作  者:   LIU M, ZHANG LX, HAN PX, HAN XQ, DU HP, YUE XY, ZHANG ZY, ZHANG H, CUI GL
  • 作者关键词:  
  • 出版物名称:   PARTICLE PARTICLE SYSTEMS CHARACTERIZATION
  • ISSN:   0934-0866 EI 1521-4117
  • 通讯作者地址:   Qingdao Univ
  • 被引频次:   33
  • DOI:   10.1002/ppsc.201500095
  • 出版年:   2015

▎ 摘  要

Niobium nitride/nitrogen-doped graphene nanosheet hybrid materials are prepared by a simple hydrothermal method combined with ammonia annealing and their electrochemical performance is reported. It is found by scanning electron microscopy (SEM) and transmission electron microscopy (TEM) that the as-obtained niobium nitride nanoparticles are about 10-15 nm in size and homogeneously anchored on graphene. A non-aqueous lithium-ion capacitor is fabricated with an optimized mass loading of activated carbon cathode and the niobium nitride/nitrogen-doped graphene nanosheet anode, which delivers high energy densities of 122.7-98.4 W h kg(-1) at power densities of 100-2000 W kg(-1), respectively. The capacity retention is 81.7% after 1000 cycles at a current density of 500 mA g(-1). The high energy and power of this hybrid capacitor bridges the gap between conventional high specific energy lithium-ion batteries and high specific power electrochemical capacitors, which holds great potential applications in energy storage for hybrid electric vehicles.