• 文献标题:   Preparation of a Dispersible Graphene
  • 文献类型:   Article
  • 作  者:   MA WS, ZHOU JW
  • 作者关键词:   gammaaminopropyltriethoxysilane, graphite oxide, graphene, dispersible
  • 出版物名称:   CHEMICAL JOURNAL OF CHINESE UNIVERSITIESCHINESE
  • ISSN:   0251-0790
  • 通讯作者地址:   S China Univ Technol
  • 被引频次:   15
  • DOI:  
  • 出版年:   2010

▎ 摘  要

Graphene is a functional material with manifold excellent perfomances, however, its chemical in-active have been hampering its development. The preparation of dispersible graphene is an important mean to the application of graphene. A functionalized graphene (FG) was prepared by treatment of graphite oxide (GO) with gamma-aminopropyl-triethoxysilane, and then reduced by hydrazine hydrate. The functionalized graphene without dried can be stable dispersed in DMF/H2O(9:1, volume ratio) and acetone/H2O (9:1, volume ratio), and the suspension of functionalized graphene in DMF/H2O(9:1, volume ratio) can also be dispersed in ethanol or acetone. Infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD) were used to characterize the structures of FGO and FG. The results show that the amino on the KH-550 reacted with carboxyl of graphite oxide generating amide, and happened addition reaction with epoxy of graphite oxide. The dried functionalized graphene layers bond with S-1-O-S-1.