• 文献标题:   Multifunctional phase change microcapsules based on graphene oxide Pickering emulsion for photothermal energy conversion and superhydrophobicity
  • 文献类型:   Article
  • 作  者:   ZHAO QH, YANG WB, LI YS, HE ZY, LI YJ, ZHOU YL, WANG RC, FAN JH, ZHANG K
  • 作者关键词:   multifunctional phase change microcapsule, pickering emulsion, photothermal energy conversion, superhydrophobicity, selfcleaning
  • 出版物名称:   INTERNATIONAL JOURNAL OF ENERGY RESEARCH
  • ISSN:   0363-907X EI 1099-114X
  • 通讯作者地址:   Southwest Univ Sci Technol
  • 被引频次:   3
  • DOI:   10.1002/er.5224
  • 出版年:   2020

▎ 摘  要

In order to enlarge the applications of microencapsulated phase change materials (microPCMs), the novel stearic acid (SA)@graphene oxide (GO)/melamine-formaldehyde (MF) multifunctional superhydrophobic microPCMs were prepared with the method of condensation polymerization. We have made a systematical study of the effects of GO content on the SA@GO/MF microPCMs. The morphology and chemical composition characterizations showed the successful fabrication of microcapsules. The differential scanning calorimeter (DSC) identified that microPCMs could store latent heat energy. According to the contact angles (CA) measurement, the microPCMs displayed the water contact angle of 160.2 degrees, which possessed the superhydrophobic property. Moreover, the self-cleaning property of SA@GO/MF microPCMs was demonstrated by designing self-cleaning experiment. The simulated irradiation experiment showed the good photothermal conversion performance of microPCMs. Owing to photothermal energy conversion performance and superhydrophobicity, multifunctional phase change microcapsules could have vital potentials in energy conversion and self-cleaning.