• 文献标题:   Pseudocapacitive Transparent/Flexible Supercapacitor based on Graphene wrapped Ni(OH)(2) Nanosheet Transparent Film Produced using Scalable Bio-inspired Methods
  • 文献类型:   Article
  • 作  者:   LI N, HUANG XK, LI RJ, CHEN YM, LI YY, SHI ZC, ZHANG HY
  • 作者关键词:   energy storage, flexible, transparent, supercapacitor, ni oh 2
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Guangdong Univ Technol
  • 被引频次:   20
  • DOI:   10.1016/j.electacta.2016.09.146
  • 出版年:   2016

▎ 摘  要

High specific-capacity pseudocapacitive transition-metal-hydroxide (TMH) materials are desirable for future high performance transparent supercapacitors, but have been rarely reported previously. The successful synthesis of TMH materials with desired nanostructures is a key factor for their transparency. Here, Ni(OH)(2) nanosheet transparent film (NNS-TF) was developed simply through a gas-liquid diffusion method. The nanostructures were enwrapped in graphene shells (NNS@Gr-TF) for using as transparent electrodes. The unique encapsulation structures build up rapid three-dimensional electron and ion transport pathways together with the underlying ITO layer. The specific areal capacitance (18.9 mF/cm(2) at 0.1 mA/cm(2)) was greatly improved, at least a thousand times higher than the reported value for transparent devices based on planer CVD graphene, and ten times as that for 3D micro-structured graphene membrane. (C) 2016 Published by Elsevier Ltd.