• 文献标题:   Durability study of platinum nanoparticles supported on gas-phase synthesized graphene in oxygen reduction reaction conditions
  • 文献类型:   Article
  • 作  者:   BERTIN E, MUNZER A, REICHENBERGER S, STREUBEL R, VINNAY T, WIGGERS H, SCHULZ C, BARCIKOWSKI S, MARZUN G
  • 作者关键词:   pulsed laser ablation in liquid, graphene, gasphase synthesi, microwave plasma reactor, platinum nanoparticle, oxygen reduction reaction
  • 出版物名称:   APPLIED SURFACE SCIENCE
  • ISSN:   0169-4332 EI 1873-5584
  • 通讯作者地址:   Univ Duisburg Essen
  • 被引频次:   6
  • DOI:   10.1016/j.apsusc.2018.10.061
  • 出版年:   2019

▎ 摘  要

Ligand-free platinum nanoparticles were prepared by pulsed laser ablation in liquids (PLAL) and employed as a benchmarking catalyst to evaluate the durability of a new gas-phase synthesized graphene support in oxygen reduction conditions. Raman measurements showed that the graphene, as compared to Vulcan, was almost defect free. Transmission electron microscopy and initial electrochemically active surface area measurements confirmed good dispersion of the catalysts on both supports. During durability tests, graphene supported Pt nanoparticles showed much better ECSA retention (75% on graphene as compared to 38% on Vulcan), ultimately retaining a higher ECSA than a commercial sample subjected to the same procedure.