• 文献标题:   In situ synthesis of monomer casting nylon-6/reduced graphene oxide nanocomposites: Intercalation structure and electrically conductive properties
  • 文献类型:   Article
  • 作  者:   XIANG M, LI CJ, YE L
  • 作者关键词:   monomer casting nylon6 mc nylon6, reduced graphene oxide rgo, anchoring effect, intercalation structure, electrically conductive network
  • 出版物名称:   JOURNAL OF INDUSTRIAL ENGINEERING CHEMISTRY
  • ISSN:   1226-086X EI 1876-794X
  • 通讯作者地址:   Sichuan Univ
  • 被引频次:   9
  • DOI:   10.1016/j.jiec.2017.02.005
  • 出版年:   2017

▎ 摘  要

Based on the industrialized reduced graphene oxide (RGO) product, MC nylon-6/RGO composites were in situ synthesized through anchoring effect of polyetheramine (PEA). Nylon-6 chains were confirmed to intercalate into RGO layers with high grafting ratio by formation of covalent bond and intermolecular hydrogen bond. By presence of PEA, RGO was well exfoliated by the nylon-6 chains and the average layer thickness increased remarkably. Moreover, the stacking of RGO layers was much more weakened and exhibited almost monolayer homogenous dispersion state in the matrix, resulting in the establishment of the electrically conductive network with a low threshold percolation. (C) 2017 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.