• 文献标题:   Facial synthesis of carbon-coated ZnFe2O4/graphene and their enhanced lithium storage properties
  • 文献类型:   Article
  • 作  者:   YAO LB, SU QM, XIAO YL, HUANG M, LI HJ, DENG HH, DU GH
  • 作者关键词:   graphene, transition metal oxide, carbon coating, nanocomposite, lithium ion batterie, energy storage
  • 出版物名称:   JOURNAL OF NANOPARTICLE RESEARCH
  • ISSN:   1388-0764 EI 1572-896X
  • 通讯作者地址:   Shaanxi Univ Sci Technol
  • 被引频次:   3
  • DOI:   10.1007/s11051-017-3935-2
  • 出版年:   2017

▎ 摘  要

Carbon-coated ZnFe2O4 spheres with sizes of similar to 110-180 nm anchored on graphene nanosheets (ZF@C/G) are successfully prepared and applied as anode materials for lithium ion batteries (LIBs). The obtained ZF@C/G presents an initial discharge capacity of 1235 mAh g(-1) and maintains a reversible capacity of 775 mAh g(-1) after 150 cycles at a current density of 500 mA g(-1). After being tested at 2 A g(-1) for 700 cycles, the capacity still retains 617 mAh g(-1). The enhanced electrochemical performances can be attributed to the synergetic role of graphene and uniform carbon coating (similar to 3-6 nm), which can inhibit the volume expansion, prevent the pulverization/aggregation upon prolonged cycling, and facilitate the electron transfer between carbon-coated ZnFe2O4 spheres. The electrochemical results suggest that the synthesized ZF@C/G nanostructures are promising electrode materials for high-performance lithium ion batteries.