• 文献标题:   Poly(ortho-aminophenol)/graphene nanocomposite as an efficient supercapacitor electrode
  • 文献类型:   Article
  • 作  者:   HELI H, YADEGARI H
  • 作者关键词:   poly orthoaminophenol, graphene, nanocomposite, electrochemical supercapacitor, synergism effect
  • 出版物名称:   JOURNAL OF ELECTROANALYTICAL CHEMISTRY
  • ISSN:   1572-6657 EI 1873-2569
  • 通讯作者地址:   Shiraz Univ Med Sci
  • 被引频次:   12
  • DOI:   10.1016/j.jelechem.2013.12.010
  • 出版年:   2014

▎ 摘  要

Poly(ortho-aminophenol)/graphene nanocomposite was electrochemically synthesized. The nanocomposite represented an excellent supercapacitive behavior resulted from the complementary properties of graphene and the conducting polymer. The nanocomposite was characterized by various methods including scanning electron microscopy, transmission electron microscopy, FT-IR spectroscopy, X-ray diffraction, cyclic voltammetry and electrochemical impedance spectroscopy techniques. As an electrode material, the specific capacitance of the nanocomposite was 281.1 F g(-1) which was about 3 times of the specific capacitance of graphene. This behavior was related to a synergistic effect of the electrical double layer capacitance of graphene and pseudo-capacitance of the conducting polymer. The nanocomposite kept >99% of the initial specific capacitance after 1200 charge/discharge cycles at a current density of 1 A g(-1). (C) 2013 Elsevier B.V. All rights reserved.