• 文献标题:   Carboxylated graphene-TiO2 hybrids as multifunctional materials: from photocatalysis to peroxidase alternatives
  • 文献类型:   Article
  • 作  者:   SARRO M, CERRUTI M, CALZA P, ANFOSSI L
  • 作者关键词:  
  • 出版物名称:   RSC ADVANCES
  • ISSN:   2046-2069
  • 通讯作者地址:   Univ Turin
  • 被引频次:   1
  • DOI:   10.1039/c6ra07808g
  • 出版年:   2016

▎ 摘  要

We synthetized hybrid materials with multifunctional properties by coupling graphene nanoplatelets (GNP) modified with carboxylic groups to titanium dioxide (TiO2) nanoparticles (NPs) and tested them both as photocatalysts to promote pollution abatement and as tracers of the presence of a model antigen (bovine serum albumin, BSA) in immunochemical assays. The presence of carboxylic groups proved to be crucial in both applications: they improved TiO2 photocatalytic activity by the interaction between the carboxylic groups on the GNP surface and the hydroxyl groups on TiO2 surface, and allowed for covalently binding the material to BSA. The photoactivity of the materials was exploited for the oxidation of 3,3',5,5'-tetramethylbenzidine for immunochemical applications.