• 文献标题:   A new mild, clean and highly efficient method for the preparation of graphene quantum dots without by-products
  • 文献类型:   Article
  • 作  者:   ZHU C, YANG SW, WANG G, MO RW, HE P, SUN J, DI ZF, KANG ZH, YUAN NY, DING JN, DING GQ, XIE XM
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY B
  • ISSN:   2050-750X EI 2050-7518
  • 通讯作者地址:   Changzhou Univ
  • 被引频次:   39
  • DOI:   10.1039/c5tb01093d
  • 出版年:   2015

▎ 摘  要

We demonstrated that graphene oxide (GO) can be oxidized and cut into graphene quantum dots (GQDs) by hydroxyl radicals ((OH)-O-center dot), which is obtained by the catalytic decomposition of hydrogen peroxide (H2O2) with a tungsten oxide nanowire (W18O49) catalyst. The clean oxidizing agent (H2O2) and the solid catalyst lead to a simple GQD preparing method without any by-products. The obtained GQD aqueous solution can be directly applied to fluorescence imaging in vitro without any further purification. The effect of the W18O49 catalyst on the (OH)-O-center dot formation is discussed, and the size of GQDs can be controlled via changing the concentration of hydroxyl radicals.