• 文献标题:   Eddy Current Measurement of Chemiresistive Sensing Transients in Graphene-hBN Heterostructures
  • 文献类型:   Article
  • 作  者:   DOSHI M, ZHANG J, FAHRENTHOLD EP
  • 作者关键词:   2d material, gas sensor, graphene, hbn, heterostructure
  • 出版物名称:   ACS SENSORS
  • ISSN:   2379-3694
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1021/acssensors.2c01845 EA DEC 2022
  • 出版年:   2023

▎ 摘  要

The development of graphene-based electronic and gas sensing devices has motivated considerable research interest in the properties of graphene-hBN heterostructures. Eddy current measurements of the sheet conductance of graphene-hBN heterostructures show a relatively low conductance, as compared to results previously reported in the literature, all of which were obtained using contact-based measurement methods. Chemiresis-tive measurements of the graphene-hBN heterostructure response to oxygen adsorption, including hysteric effects under transient multicycle loading, show that the incremental sheet conductance responses of graphene and graphene-hBN sensors differ in sign. A transient, nonlinear, history dependent constitutive model of graphene-hBN response to oxygen adsorption distinguishes stochastic variations in material properties from deterministic variations in sensor performance. The deterministic variations are due to sensing process hysteresis, a phenomenon of central interest in the development of graphene-based sensor systems.