• 文献标题:   Vertical Graphene Film Enables High-Performance Quasi-Solid-State Planar Zinc-Ion Microbatteries
  • 文献类型:   Article, Early Access
  • 作  者:   ZHOU YM, LI WY, XIE YH, DENG LY, KE BY, JIAN YJ, CHENG SY, QU BH, WANG XH
  • 作者关键词:   vertical graphene, zincion battery, microbattery, electrodeposition, flexible
  • 出版物名称:   ACS APPLIED MATERIALS INTERFACES
  • ISSN:   1944-8244 EI 1944-8252
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1021/acsami.2c22043 EA FEB 2023
  • 出版年:   2023

▎ 摘  要

With the advantages of low cost, high safety, and environmental friendliness, quasi-solid-state zinc-ion microbatteries (ZIMBs) have received widespread attention in the field of flexible wearable devices and on-chip integratable energy storage. However, hysteresis Zn-ion transport kinetics and inhomogeneous growth of the zinc anode result in the poor capacity reversibility and cycling stability. Herein, a quasi-solid-state planar zinc-ion cell was developed by employing a vertical graphene (VG) film as an effective conductive modification layer for both the cathode and anode. The VG distinctly induces uniform Zn deposition/stripping, accelerates the charge transport, and enhances the adhesion between the active materials and current collectors. As a result, planar Zn@VG//MnO2@VG exhibits a high areal capacity of 159 mu Ah cm-2, a remarkably high areal energy/power density of 201.5 mu Wh cm-2/67.16 mu W cm-2, and a high capacity retention of 95.6% at a bending angle of 180 degrees. The proposed facile strategy for electrode modification provides a new insight into the design of high-performance flexible and planar ZIMBs.