• 文献标题:   Spiral wire-type stretchable all-solid-state supercapacitors based on MnO2/graphene/Ni wires
  • 文献类型:   Article
  • 作  者:   ZHANG M, LIU YH, HU ML, WEI HL, GAO YH
  • 作者关键词:   supercapacitor, stretchable, mno2, buffer layer
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Huazhong Univ Sci Technol
  • 被引频次:   9
  • DOI:   10.1016/j.electacta.2017.09.106
  • 出版年:   2017

▎ 摘  要

Here, we report all-solid-state spiral wire-type stretchable supercapacitors (WSSCs) based on wire-type MnO2/graphene (Gr)/Ni electrode, in which a corroded Ni wire serves as substrate, Gr as buffer layer for depositing of MnO2 and KOH-polyvinyl alcohol gel as the solid-state electrolyte. Through interface engineering (surface corrosion and addition of buffer layer), interface contact, equivalent series resistance (ESR) and electrochemical performance of the wire-type electrode are greatly improved. The WSSC exhibits good electrochemical performance and stretchability. Linear (volumetric) specific capacitance of the spiral WSSC reaches 31.48 mF cm(-1) (0.45 F cm(-3)). Maximum linear energy density (power density) reaches 2.80 mu Wh cm(-1) (0.54 mW cm(-1)). The capacitance retention is about 92% after deformed at 100% tensile strain. Furthermore, the spiral WSSC has a smaller size and can be easily integrated with electrical wire in electric equipment as a backup power supply, which avoid damage of device or data as sudden power failure occurs. (C) 2017 Elsevier Ltd. All rights reserved.