• 文献标题:   Significantly enhanced photocatalytic performance of ZnO via graphene hybridization and the mechanism study
  • 文献类型:   Article
  • 作  者:   XU TG, ZHANG LW, CHENG HY, ZHU YF
  • 作者关键词:   graphene, photocatalysi, zno, photoelectrochemical
  • 出版物名称:   APPLIED CATALYSIS BENVIRONMENTAL
  • ISSN:   0926-3373 EI 1873-3883
  • 通讯作者地址:   Tsinghua Univ
  • 被引频次:   782
  • DOI:   10.1016/j.apcatb.2010.10.007
  • 出版年:   2011

▎ 摘  要

Graphene hybridized with ZnO could produce an efficient photocatalyst. The ZnO nanoparticles were firstly coated with an appropriate amount of graphene oxide, the graphene oxide was then in situ reduced to form the ZnO/graphene composite. Graphene hybridized ZnO photocatalyst showed enhanced photocatalytic activity for the degradation of organic dye. The degree of photocatalytic activity enhancement strongly depended on the coverage of graphene on the surface of ZnO nanoparticles. The sample of 2 wt% graphene hybridized ZnO showed the highest photocatalytic activity, which was about 4 times as that of pristine ZnO. The enhancement of photocatalytic activity was attributed to the high migration efficiency of photo-induced electrons and the inhibited charge carriers recombination due to the electronic interaction between ZnO and graphene. The electronic interaction was systematically studied and confirmed by the photoelectrochemical measurements. (C) 2010 Elsevier B.V. All rights reserved.