• 文献标题:   Porous graphene supported Pt catalysts for proton exchange membrane fuel cells
  • 文献类型:   Article
  • 作  者:   CHENG K, HE DP, PENG T, LV HF, PAN M, MU SC
  • 作者关键词:   pem fuel cell, catalyst, electrode, pore, graphene
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Wuhan Univ Technol
  • 被引频次:   30
  • DOI:   10.1016/j.electacta.2014.03.181
  • 出版年:   2014

▎ 摘  要

Graphene nanosheet (GNS) has a remarkably high ratio of surface area to thickness and intense inter-sheet aggregation, which heavily resist mass diffusion in vertical orientation. Here, we establish a fast-speed mass diffusion passage by creating pores in GNS, and the corresponding Pt catalyst (Pt/rPGO) displays 15.5 times mass diffusion rate than that of the pristine GNS supported Pt catalyst (Pt/rGO). Thus, the Pt/rPGO catalyst exhibits 1.5 times increase in Pt mass activity toward oxygen reduction reaction compared with the Pt/rGO. Significantly, after H-2 thermal treatment, the mass activity of the Pt/rPGO further increases to 1.9 times that of the Pt/rGO, and its electrochemical stability is also greatly improved. (C) 2014 Elsevier Ltd. All rights reserved.