• 文献标题:   Terminalia bellirica mediated one-pot green synthesis of reduced graphene oxide-silver nanoparticle (RGO/AgNP) nanocomposite and its catalytic activity towards p-nitrophenol reduction in water
  • 文献类型:   Article
  • 作  者:   KADIYALA NK, MANDAL BK
  • 作者关键词:   rgo/agnp nanocomposite, terminalia bellirica, green synthesi, 4np reduction
  • 出版物名称:   JOURNAL OF THE INDIAN CHEMICAL SOCIETY
  • ISSN:   0019-4522
  • 通讯作者地址:   VIT Univ
  • 被引频次:   0
  • DOI:  
  • 出版年:   2016

▎ 摘  要

We report a facile environmentally friendly one-pot synthetic route for the preparation of RGO/AgNP nanocomposite using Terminalia bellirica (T. bellirica) fruit extract as a reducing and stabilizing agent. The phenolic constituents of T. bellirica fruit extract played a key role in the reduction of both GO and Ag+ ions followed by uniform decoration of AgNPs onto the RGO surface. The obtained nanocomposite was characterized by UV-Visible, FTIR, XRD, SEM-EDS, TEM-SAED and Raman spectroscopy. The resultant nanocomposite exhibited excellent catalytic activity towards the reduction of 4-NP to 4-AP in the presence of NaBH4 as reducing agent in water. The reduction reaction obeyed pseudo-first order kinetics and the rate constant was increased with increasing catalytic doses.. Mechanisms for the synthesis of RGO/AgNP nanocomposite and catalytic reduction of 4-NP are discussed. This is a simple and low cost method for the fabrication of highly active catalyst material for the reduction of anthropogenic pollutant 4-NP in water.