• 文献标题:   Ionic Liquid Supported on Magnetic Graphene Oxide as a Highly Efficient and Stable Catalyst for the Synthesis of Triazolopyrimidines
  • 文献类型:   Article
  • 作  者:   JAHANBAKHSHI A, FARAHI M, AGHAJANI Y
  • 作者关键词:   ionic liquid, graphene oxide, triazolopyrimidine, fe 3 o 4
  • 出版物名称:   ACTA CHIMICA SLOVENICA
  • ISSN:   1318-0207 EI 1580-3155
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.17344/acsi.2022.7593
  • 出版年:   2022

▎ 摘  要

A novel sulfonic acid functionalized ionic liquid was prepared by anchoring 1-(propyl-3-sulfonate) vinylimidazolium hydrogen sulfate ([(CH2)3SO3HVIm]HSO4) on Fe3O4@GO. The prepared heterogeneous catalyst was characterized by XRD, FT-IR, EDX, SEM, VSM and TGA techniques. The results show that [(CH2)3SO3HVIm]HSO4 was successful-ly deposited on the surface of Fe3O4@GO and the prepared ionic liquid catalyst exhibited good thermal stability. The activity of the prepared catalyst was investigated in the synthesis of triazolo[1,5-a]pyrimidine derivatives by a one-pot three-component reaction of active methylene compound (malononitrile or ethyl cyanoacetate), 3-amine-1H-1,2,4-tri-azole and aryl aldehydes under solvent-free conditions. This catalyst could be rapidly separated by an external magnet and recycled seven times without significant loss of catalytic activity.