• 文献标题:   ZIF-8 modified graphene oxide/sodium alginate 3D elastic spheres for uranium trapping in seawater
  • 文献类型:   Article
  • 作  者:   CHANG X, HU PZ, LIU HL, LV ZX, YANG JY, WANG JL, LI Z, QIAN LJ, WU WS
  • 作者关键词:   adsorption, graphene composite sphere, elastic swelling, seawater
  • 出版物名称:   DESALINATION
  • ISSN:   0011-9164 EI 1873-4464
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1016/j.desal.2023.116371 EA JAN 2023
  • 出版年:   2023

▎ 摘  要

Due to the popularization of nuclear energy and the application of nuclear technology, there is an increasing demand for uranium resources. Extraction of uranium from seawater has become a hot topic. To achieve uranium capture, a three-dimensional carbon structure material (GO/ZIF-8@SA) with ionic stress elastic expansion consisting of graphene oxide, ZIF-8 and sodium alginate was developed. Surface morphological characteristics and elemental composition evaluation were determined by using SEM. The doping concentration of the elements in the synthesized products was measured by EDS. XRD, FT-IR and XPS confirmed the successful doping of ZIF-8. In seawater spiked with uranium, GO/ZIF-8@SA showed not only an ultra-high adsorption capacity of 1897 mg center dot g(-1) for U(VI), but also a high selectivity. Interestingly, the volume of GO/ZIF-8@SA can be elastically expanded with the adsorption of U(VI). The expanded microspheres can be directly captured from the seawater by the mesh sieve. GO/ZIF-8@SA solves the problem of balancing adsorption capacity and selectivity in a complex seawater environment, which gives it great potential for application in seawater uranium extraction.