• 文献标题:   Graphene Sandwich Stable Perovskite Quantum-Dot Light-Emissive Ultrasensitive and Ultrafast Broadband Vertical Phototransistors
  • 文献类型:   Article
  • 作  者:   BERA KP, HAIDER G, HUANG YT, ROY PK, INBARAJ CRP, LIAO YM, LIN HI, LU CH, SHEN C, SHIH WY, SHIH WH, CHEN YF
  • 作者关键词:   vertical phototransistor, led, perovskite quantum dot, graphene, broadband photoresponse
  • 出版物名称:   ACS NANO
  • ISSN:   1936-0851 EI 1936-086X
  • 通讯作者地址:   Natl Taiwan Univ
  • 被引频次:   10
  • DOI:   10.1021/acsnano.9b03165
  • 出版年:   2019

▎ 摘  要

Dual-functional devices that can simultaneously detect light and emit light have a tremendous appeal for multiple applications, including displays, sensors, defense, and high-speed optical communication. Despite the tremendous efforts of scientists, the progress of integration of a phototransistor, where the built-in electric field separates the photogenerated excitons, and a light-emitting diode, where the radiative recombination can be enhanced by band offset, into a single device remains a challenge. Combining the superior properties of perovskite quantum dots (PQDs) and graphene, here we report a light-emissive, ultrasensitive, ultrafast, and broadband vertical phototransistor that can simultaneously act as an efficient photodetector and light emitter within a single device. The estimated value of the external quantum efficiency of the vertical phototransistor is similar to 1.2 X 10(10)% with a photoresponsivity of >10(9) A W-1 and a response time of <50 mu s, which exceed all the presently reported vertical phototransistor devices. We also demonstrate that the modulation of the Dirac point of graphene efficiently tunes both amplitude and polarity of the photocurrent. The device exhibits a green emission having a quantum efficiency of 5.6%. The moisture-insensitive and environmentally stable, light-emissive, ultrafast, and ultrasensitive broadband phototransistor creates a useful route for dual-functional optoelectronic devices.