• 文献标题:   Imidazole-aryl coupling reaction via C-H bond activation catalyzed by palladium supported on modified magnetic reduced graphene oxide in alkaline deep eutectic solvent
  • 文献类型:   Article
  • 作  者:   SHARIATIPOUR M, SALAMATMANESH A, NEJAD MJ, HEYDARI A
  • 作者关键词:   ch arylation, imidazole, heterogeneous catalyst, magnetic reduced graphene oxide, palladium, deep eutectic solvent
  • 出版物名称:   CATALYSIS COMMUNICATIONS
  • ISSN:   1566-7367 EI 1873-3905
  • 通讯作者地址:   Tarbiat Modares Univ
  • 被引频次:   3
  • DOI:   10.1016/j.catcom.2019.105890
  • 出版年:   2020

▎ 摘  要

By employing reusable heterogeneous catalyst, modified magnetic reduced graphene oxide-supported palladium catalyst (MRGO@ DAP- AO-Pd-II), the regioselective C-5 arylation of imidazoles via C-H bond activation pathway for the preparation of C5-arylated imidazoles has been successfully achieved in alkaline deep eutectic solvent made of potassium carbonate and glycerol under aerobic conditions. Compared to previous procedures, significant improvements of this new protocol demonstrated by the high catalytic efficiency, easy recovery of catalyst, broad substrate scope and sustainable reaction condition using green solvent.