• 文献标题:   Boosting ethanol electrooxidation via photothermal effect over palladium/reduced graphene oxide
  • 文献类型:   Article
  • 作  者:   WU YM, HAN SH, HUANG Y, SHI YM, ZHANG B
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY A
  • ISSN:   2050-7488 EI 2050-7496
  • 通讯作者地址:   Tianjin Univ
  • 被引频次:   2
  • DOI:   10.1039/c8ta08006b
  • 出版年:   2018

▎ 摘  要

A photothermal effect strategy to combine the model thermal material, namely, reduced graphene oxide with active species (palladium) was developed to greatly improve the activity and stability of ethanol electrooxidation reaction (EOR). The improvement can be ascribed to both accelerated reaction kinetics of EOR and promoted desorption of the toxic reaction intermediate COads from active palladium caused by the efficient light absorption and subsequent conversion to thermy of reduced graphene oxide. Additionally, this photothermally enhanced strategy was found to be suitable for electrooxidation reactions of other alcohols (e.g., ethylene glycol and glycerol).