• 文献标题:   Enhanced water permeation based on nanoporous multilayer graphene membranes: the role of pore size and density
  • 文献类型:   Article
  • 作  者:   KIM DW, CHOI J, KIM D, JUNG HT
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY A
  • ISSN:   2050-7488 EI 2050-7496
  • 通讯作者地址:   Korea Adv Inst Sci Technol
  • 被引频次:   20
  • DOI:   10.1039/c6ta06381k
  • 出版年:   2016

▎ 摘  要

Bulk scale graphenes containing narrow and dense pores are realized via potassium hydroxide activation of pre-oxidized graphite (size: ca. 3 nm, density: ca. 10(15) m(-2)). A film (20 nm thickness) comprised of this nanoporous graphene displays much enhanced water flux (ca. 37 L m(-2) h(-1) bar(-1)) compared to that of conventional graphene oxide membranes (similar to 6 times), while maintaining the seiving performances of GO laminates with ca. 20% rejection for NaCl and up to 99% rejection for various dyes around 1 nm diameter size. This advantageous property is a result of the fact that in addition to the effect of the interlayer stacking of graphene sheets, nanopores in the graphene generated by using the new method serve as additional channels through which water molecules can diffuse. We believe that the new approach will play a key role in preparing and designing graphene membranes with high flux.