• 文献标题:   Chemical Amination via Cycloaddition of Graphene for Use in a Glucose Sensor
  • 文献类型:   Article
  • 作  者:   QIN H, HWANG T, AHN C, KIM JA, JIN Y, CHO Y, SHIN C, KIM T
  • 作者关键词:   aminated graphene, cycloaddition, chemical vapour deposition, sensor
  • 出版物名称:   JOURNAL OF NANOSCIENCE NANOTECHNOLOGY
  • ISSN:   1533-4880 EI 1533-4899
  • 通讯作者地址:   Sungkyunkwan Univ
  • 被引频次:   3
  • DOI:   10.1166/jnn.2016.12231
  • 出版年:   2016

▎ 摘  要

Graphene was chemically aminated via cycloaddition. Aziridine-ring linkages were formed by covalently modifying the C-C double bonds in graphene. The aminated graphene presents an enhanced hydrophilicity, the contact angle with water decreases from 80.5 degrees to 58.5 degrees. And the conductivity of aminated graphene exhibits exponential decay as the reaction time increase. If the reaction time is 90 min, the resistance of aminated graphene was increased from similar to 32 Omega to similar to 2744 Omega. Because the amino group has good biocompatibility, the aminated graphene is designed for use as an enzyme sensor platform, such as glucose sensor based on glucose oxidase. The aminated graphene exhibited a good detection response for glucose. The increase in device current is about 12% in 1.2 mg/mL glucose solution.