• 文献标题:   Facile synthesis of copper hexacyanoferrate/graphene nanocomposite for electrochemical energy storage
  • 文献类型:   Article
  • 作  者:   TARGHOLI E, RAHMANIFAR MS, MOUSAVIKHOSHDEL SM
  • 作者关键词:   copper hexacyanoferrate, graphene, nanocomposite, supercapacitor
  • 出版物名称:   APPLIED ORGANOMETALLIC CHEMISTRY
  • ISSN:   0268-2605 EI 1099-0739
  • 通讯作者地址:   Iran Univ Sci Technol
  • 被引频次:   0
  • DOI:   10.1002/aoc.4615
  • 出版年:   2018

▎ 摘  要

A two-component nanocomposite of copper hexacyanoferrate/reduced graphene oxide (CuHCF/rGO) was successfully synthesized using a solution-based co-precipitation process in the presence of graphene oxide solution. Electrochemical measurements indicated a specific capacitance of 548 F g(-1) at a current density of 0.5 A g(-1) in the potential range of -0.2 to 1 V, versus Ag/AgCl standard electrode, obtained in an electrolyte of 0.5 M K2SO4 (as a neutral electrolyte) during galvanostatic charge/discharge cycles. This value is higher than the specific capacitance of the raw materials rGO (174 F g(-1) at a current density of 0.5 A g(-1)) and CuHCF (236 F g(-1) at a current density of 0.5 A g(-1)), which is rooted in the activation of copper ions in the electrochemical reaction and some synergistic effects (observed between rGO and CuHCF). The rGO/CuHCF nanocomposite electrode was able to retain 83% of its initial capacitance after 1000 cycles at a current density of 3 A g(-1).