• 文献标题:   Room-Temperature One-Step Synthesis of Silver/Reduced Graphene Oxide Nanocomposites as an Excellent Microwave Absorber
  • 文献类型:   Article
  • 作  者:   MONDAL J, SRIVASTAVA SK
  • 作者关键词:  
  • 出版物名称:   LANGMUIR
  • ISSN:   0743-7463
  • 通讯作者地址:  
  • 被引频次:   2
  • DOI:   10.1021/acs.langmuir.1c02110 EA NOV 2021
  • 出版年:   2021

▎ 摘  要

The present study is focused on room-temperature synthesis carried out by reduction of an aqueous silver nitrate (AgNO3) and AgNO3/graphene oxide (GO) dispersion using a low-cost commercial Fehling B solution in one step to form silver quantum dots (Ag QDs) and their Ag/reduced graphene oxide (Ag/RGO) nanocomposites and their characterization. The crystallinity, surface chemistry, structural, and morphological studies indicated the formation of crystalline small-sized quasispherical-functionalized Ag particles distributed uniformly on the surface of RGO. The conductivity measurements further showed an improvement in the conductivity of Ag/RGO nanocomposites as compared to neat Ag QDs. Our findings showed that Ag/RGO nanocomposites prepared by using 0.055 wt % of GO exhibited a total enhanced electromagnetic interference (EMI)-shielding efficiency (SET) of similar to 39.2-42.3 dB (2-8 GHz) with a maximum value of similar to 43.8 dB at 7. 5 GHz due to conduction loss, an interconnected conducting network, and a synergistic effect, and it followed an absorption mechanism. Furthermore, this superior absorption-dominated shielding conferred reflection loss (R-L) in the range of -79 to -82.5 dB with a R-L minima of -88 dB at 7.5 GHz, considering an effective absorption bandwidth of similar to 6 GHz with 99.9% absorptivity. It is anticipated that Ag/RGO nanocomposites prepared in one step at room temperature could find potential EMIshielding applications.