• 文献标题:   Highly conductive chemically converted graphene prepared from mildly oxidized graphene oxide
  • 文献类型:   Article
  • 作  者:   XU YX, SHENG KX, LI C, SHI GQ
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY
  • ISSN:   0959-9428 EI 1364-5501
  • 通讯作者地址:   Tsinghua Univ
  • 被引频次:   126
  • DOI:   10.1039/c1jm10768b
  • 出版年:   2011

▎ 摘  要

Mildly oxidized graphene oxide (MOGO) was achieved by chemical exfoliation of graphite through a modified Hummers' method. The MOGO is not only able to be stably dispersed in water at a high concentration (1 mg mL(-1)), but also preserves the highly crystalline structure of the conjugated carbon framework. Thus, the MOGO can be used as a low-defect precursor to prepare highly conductive graphene by chemical reduction. The electrical conductivity of hydrazine or hydriodic acid reduced MOGO was measured to be 169 or 405 S cm(-1). This value is about 3 times that of the chemically converted graphene (CCG) prepared by reducing the conventional graphene oxide via Hummers' method with the same reducing agent. This work not only develops a facile route to high-throughput preparation of processable high-quality CCG, but also provides a deeper understanding of the crucial influence of the degree of oxidation of graphene oxide on the electrical properties of its reduced product.