▎ 摘 要
Hollow structured cobalt phosphide nanocrystals with ultrathin shells anchored on reduced graphene oxide are successfully fabricated, holding great stability and enhanced catalytic activity for hydrogen evolution in comparison to nonhollow cobalt phosphide nanocrystals on reduced graphene oxide. The evolution mechanism of hollow structured cobalt phosphide is proposed and discussed. This work offers an active but inexpensive electrocatalyst toward hydrogen evolution reduction.