• 文献标题:   Improved cycling stability of MoS2-coated carbon nanotubes on graphene foam as flexible anodes for lithium-ion batteries
  • 文献类型:   Article
  • 作  者:   MA XX, LIU XS, ZHAO JP, HAO J, CHI CX, LIU XX, LI Y, LIU SK, ZHANG K
  • 作者关键词:  
  • 出版物名称:   NEW JOURNAL OF CHEMISTRY
  • ISSN:   1144-0546 EI 1369-9261
  • 通讯作者地址:   Harbin Inst Technol
  • 被引频次:   8
  • DOI:   10.1039/c6nj02238c
  • 出版年:   2017

▎ 摘  要

Achieving appropriate cycling stability for metal sulfides used as anodes in Li-ion batteries remains highly challenging because of structural collapse or low conductivity. Herein, a novel composite was designed as an anode material for Li-ion batteries. This unique architecture has the advantages of a large interface area, numerous channels for Li+ and electron transport, and a porous structure that facilitates electrolyte infiltration and buffers the volume expansion. As expected, this composite exhibits good cycling stability, high reversible capacity, and high rate capability, delivering a high discharge capacity of 1511.6 mA h g(-1) and a high first columbic efficiency of 83.27%. The reversible capacities of graphitic-carbon network material (GCNM) electrodes are 1112 mA h g(-1) at a current density of 0.1 A g(-1) after 100 cycles, and they show superior rate capabilities. This GCNM composite demonstrates great potential for applications in power sources for flexible and lightweight electronic devices.