• 文献标题:   Photoelectrochemical sensor based on composite of CdTe and nickel tetra-amined phthalocyanine covalently linked with graphene oxide for ultrasensitive detection of curcumin
  • 文献类型:   Article
  • 作  者:   PENG JY, HUANG Q, LIU YX, LIU PF, ZHANG CZ
  • 作者关键词:   photoelectrochemical, tgacdte@nitapcgr composite, curcumin
  • 出版物名称:   SENSORS ACTUATORS BCHEMICAL
  • ISSN:   0925-4005
  • 通讯作者地址:   Guangxi Normal Univ Nationalities
  • 被引频次:   20
  • DOI:   10.1016/j.snb.2019.05.047
  • 出版年:   2019

▎ 摘  要

A novel efficient photoelectrochemical (PEC) sensor was assembled for curcumin (Cur) detection using 2-mercaptoacetic acid (TGA)-capped CdTe nanoparticles and nickel tetra-amined phthalocyanine-linked graphene oxide (TGA-CdTe@NiTAPc-Gr). The TGA-CdTe nanoparticles could be firmly immobilized on the thin film structure of NiTAPc-Gr in a hydrogen-bonded manner, thus producing the proposed PEC sensor with a high photoelectrochemical activity of TGA-CdTe nanoparticles and excellent stability of NiTAPc-Gr. The TGA-CdTe@NiTAPc-Gr thin film showed a stronger blue light absorption property than the individual precursors, and this resulted in the sensitive detection of Cur ranging from 0.25-100 mu M with a detection limit of 12.50 nM. In addition, the PEC sensor exhibited a high sensitivity and selectivity and quite good reproducibility. Thus, it shows potential for Cur detection in real samples.