• 文献标题:   Synthesis and characterisation of hydrophilic and organophilic graphene nanosheets
  • 文献类型:   Article
  • 作  者:   WANG GX, SHEN XP, WANG B, YAO J, PARK J
  • 作者关键词:  
  • 出版物名称:   CARBON
  • ISSN:   0008-6223
  • 通讯作者地址:   Univ Wollongong
  • 被引频次:   448
  • DOI:   10.1016/j.carbon.2009.01.027
  • 出版年:   2009

▎ 摘  要

Hydrophilic graphene nanosheets were rapidly synthesized by reacting graphene oxide nanosheets with poly(sodium 4-styrene sulfonate) and simultaneously reducing by hydrazine hydrate under hydrothermal conditions. Organophilic graphene nanosheets were prepared by reacting with octadecylamine and reduction by hydroquinone through a reflux process. Ultraviolet-visible spectroscopy and Fourier transform infrared spectroscopy measurements confirmed the attachment of organic molecules to the graphene nanosheets to achieve hydrophilic and organophilic affinity. X-ray diffraction, Raman spectroscopy, and transmission electron microscopy analysis indicated that the crystal structure of the graphene nanosheets was maintained intact after chemical functionalisation. (C) 2009 Elsevier Ltd. All fights reserved.