• 文献标题:   A single-step synthesis of nitrogen-doped graphene sheets decorated with cobalt hydroxide nanoflakes for the determination of dopamine
  • 文献类型:   Article
  • 作  者:   SHAHID MM, ISMAIL AH, ALMOKARAM AMAAA, VIKNESWARAN R, AHMAD S, HAMZA A, NUMAN A
  • 作者关键词:   nitrogen doped graphene, dopamine, electrochemical sensor, amperometric detection
  • 出版物名称:   PROGRESS IN NATURAL SCIENCEMATERIALS INTERNATIONAL
  • ISSN:   1002-0071 EI 1745-5391
  • 通讯作者地址:   Univ Malaya
  • 被引频次:   7
  • DOI:   10.1016/j.pnsc.2017.09.001
  • 出版年:   2017

▎ 摘  要

Nitrogen-doped reduced graphene oxide (NrGO) sheets decorated with Co(OH)(2) nanoflakes were prepared by a single-step hydrothermal process. The morphological and structural characterizations of as synthesized NrGO@Co(OH)(2) nanoflakes were performed by field emission scanning electron microscopy (FESEM), EDX-mapping and X-ray diffraction (XRD). NrGO@Co(OH)(2) nanoflakes modified glassy carbon electrode (GCE) was used for electrochemical sensing of dopamine in neutral medium. The nanocomposite modified electrode showed enhanced electrochemical sensing ability for the detection of dopamine and the limit of detection (LoD) was found to be 0.201 mu M with a sensitivity value of 0.0286 +/- 0.002 mA mM(-1). Interference studies revealed that NrGO@Co(OH)(2)-GCE endow excellent selectivity for DA detection even in the presence of higher concentration of common co-existing physiological interfering analytes. Additionally, proposed sensor demonstrated excellent performance in urine samples with promising reproducibility and stability.