• 文献标题:   Electrochemical Sensing Performances for Uric Acid Detection on Various Amine Adlayers Used in Immobilizing Reduced Graphene Oxide
  • 文献类型:   Article
  • 作  者:   PARK S, HWANG S, TAKENAKA S, KIM K
  • 作者关键词:   amine adlayer, reduced graphene oxide, uric acid, ascorbic acid, electrocatalysi
  • 出版物名称:   ELECTROANALYSIS
  • ISSN:   1040-0397 EI 1521-4109
  • 通讯作者地址:   Incheon Natl Univ
  • 被引频次:   10
  • DOI:   10.1002/elan.201400650
  • 出版年:   2015

▎ 摘  要

We investigated an influence of amine adlayer on electrochemical sensing performances for uric acid detection on reduced graphene oxide (RGO)-decorated indium-tin oxide electrode surfaces. Various amine-terminated molecules including aminoethyl aryldiazonium cation, 2,2'-(ethylenedioxy) bis(ethylamine), 3-aminopro-pyltriethoxysilane, polyethyleneimine were introduced as adlayers to electrostatically immobilize RGO on the electrode surfaces. The anodic oxidation current of uric acid was observed on the various surfaces with differential pulse voltammetry. The current was highly enhanced by electrocatalytic activity of RGO. The sensing performances including linearity, sensitivity, limit of detection, and correlation coefficient were measured and compared. The adlayer with 3-aminopropyltriethoxysilane showed the best performances on the RGO-modified surface.