• 文献标题:   Effect of electropolymerization duration on the structure and performance of polypyrrole/graphene nanoplatelet counter electrode for dye-sensitized solar cells
  • 文献类型:   Article
  • 作  者:   OHTANI Y, KUMANO K, SANESHIGE M, TAKAMI K, HOSHI H
  • 作者关键词:   graphene, polypyrrole, electropolymerization, electrochemical impedance spectroscopy, iodide, triiodide redox reaction
  • 出版物名称:   JOURNAL OF SOLID STATE ELECTROCHEMISTRY
  • ISSN:   1432-8488 EI 1433-0768
  • 通讯作者地址:  
  • 被引频次:   2
  • DOI:   10.1007/s10008-021-04944-8 EA MAY 2021
  • 出版年:   2021

▎ 摘  要

Despite their potential for use as a low-cost energy-conversion device, dye-sensitized solar cells (DSSCs) have not been widely utilized because they apply platinum as a counter electrode, necessitating the use of an alternative, inexpensive material as a counter electrode. In this study, a polypyrrole-covered graphene nanoplatelet (PPy/GN) film was prepared by the electrochemical method, and a DSSC was synthesized using the PPy/GN film as a counter electrode. Analysis by Raman spectroscopy confirmed that the electropolymerized PPy contained oxidized PPy, and the structure of PPy could be changed by changing the duration of polymerization. The presence of oxidized PPy decreased the performance of the PPy/GN electrodes, and the charge transfer resistance between the electrolyte ion and PPy/GN decreased by decreasing the content of oxidized PPy. The conversion efficiency (eta) of the DSSCs increased with the use of PPy/GN electrodes, and a maximum eta of 4.3 % was comparable to that of the cells with sputtered Pt electrodes.