• 文献标题:   Study of complex electrodeposited thin film with multi-layer graphene-coated metal nanoparticles
  • 文献类型:   Article
  • 作  者:   CHO YL, LEE JW, PARK C, SONG YI, SUH SJ
  • 作者关键词:   complex electrodeposition, metal nanoparticle, multilayer graphenecoated cu nanoparticle, electrical wire explosion proces, corrosion resistance
  • 出版物名称:   CARBON LETTERS
  • ISSN:   1976-4251 EI 2233-4998
  • 通讯作者地址:   Sungkyunkwan Univ
  • 被引频次:   2
  • DOI:   10.5714/CL.2017.21.068
  • 出版年:   2017

▎ 摘  要

We have demonstrated the production of thin films containing multilayer graphene-coated copper nanoparticles (MGCNs) by a commercial electrodeposition method. The MGCNs were produced by electrical wire explosion, an easily applied technique for creating hybrid metal nanoparticles. The nanoparticles had average diameters of 10-120 nm and quasi-spherical morphologies. We made a complex-electrodeposited copper thin film (CETF) with a thickness of 4.8 mu m by adding 300 ppm MGCNs to the electrolyte solution and performing electrodeposition. We measured the electric properties and performed corrosion testing of the CETF. Raman spectroscopy was used to measure the bonding characteristics and estimate the number of layers in the graphene films. The resistivity of the bare-electrodeposited copper thin film (BETF) was 2.092 x 10(-6) Omega center dot cm, and the resistivity of the CETF after the addition of 300 ppm MGCNs was decreased by 2% to similar to 2.049 x 10(-6) Omega center dot cm. The corrosion resistance of the BETF was 9.306 Omega, while that of the CETF was increased to 20.04 Omega. Therefore, the CETF with MGCNs can be used in interconnection circuits for printed circuit boards or semiconductor devices on the basis of its low resistivity and high corrosion resistance.