• 文献标题:   Magnetic resonance evidence of manganese-graphene complexes in reduced graphene oxide
  • 文献类型:   Article
  • 作  者:   PANICH AM, SHAMES AI, ALEKSENSKII AE, DIDEIKIN A
  • 作者关键词:   manganesegraphene complexe, reduced graphene oxide, electron paramagnetic resonance, nuclear magnetic resonance
  • 出版物名称:   SOLID STATE COMMUNICATIONS
  • ISSN:   0038-1098
  • 通讯作者地址:   Ben Gurion Univ Negev
  • 被引频次:   28
  • DOI:   10.1016/j.ssc.2012.01.005
  • 出版年:   2012

▎ 摘  要

We report on EPR and NMR study of reduced graphene oxide (RGO) produced by the Hummers method. We show that this RGO sample reveals isolated Mn2+ ions, which originate from potassium permanganate used in the process of the sample preparation. These ions form paramagnetic charge-transfer complexes with the graphene planes and contribute to the C-13 spin lattice relaxation. (C) 2012 Elsevier Ltd. All rights reserved.