• 文献标题:   Synthesis and Study of Electrochemical Properties of Nanocomposites with Graphene-like Particles Integrated into a High-Porosity Carbon Matrix
  • 文献类型:   Article
  • 作  者:   KRYAZHEV YG, VOLFKOVICH YM, MEL NIKOV VP, RYCHAGOV AY, TRENIKHIN MV, SOLODOVNICHENKO VS, ZAPEVALOVA ES, LIKHOLOBOV VA
  • 作者关键词:   chloropolymer, nanocomposite, nanoparticle, carbon, graphenelike structure, supercapacitor
  • 出版物名称:   PROTECTION OF METALS PHYSICAL CHEMISTRY OF SURFACES
  • ISSN:   2070-2051 EI 2070-206X
  • 通讯作者地址:   Russian Acad Sci
  • 被引频次:   0
  • DOI:   10.1134/S2070205117030108
  • 出版年:   2017

▎ 摘  要

Carbon-carbon nanocomposite (CCNC) was synthesized by introducing a dispersion of reduced graphite oxide (RGO) into the reaction medium upon the synthesis of polymer with a conjugated bond system (polyvinylene), which is a product of alkaline dehydrochlorination of polyvinylchloride, followed by carbonization of the resulting adduct - RGO-polyvinylene. After activation of CCNC in the CO2 environment (900 degrees C) a high-porosity material (the specific BET surface is more than 1700 m(2)/g) with a developed volume of micro- and mesopores was obtained. According to electrochemical investigations, this material possesses a large capacity (100-200 F/g) and high performance, and, therefore, it can be applied in supercapacitor traction systems and for load leveling in electric power lines.