• 文献标题:   Photocatalytic performance of titania nanospheres deposited on graphene in coumarin oxidation reaction
  • 文献类型:   Article, Proceedings Paper
  • 作  者:   WOJTONISZAK M, ZIELINSKA B, KALENCZUK R, MIJOWSKA E
  • 作者关键词:   graphene, tio2, photocatalyst, coumarin
  • 出版物名称:   MATERIALS SCIENCEPOLAND
  • ISSN:   2083-134X
  • 通讯作者地址:   W Pomeranian Univ Technol
  • 被引频次:   14
  • DOI:   10.2478/s13536-012-0008-1
  • 出版年:   2012

▎ 摘  要

In this paper, we present a study on enhanced photocatalytic performance of TiO2 nanospheres deposited on graphene (n-TiO2-G) in a process of coumarin oxidation. The enhancement of the photoactivity has been observed in respect to commercial TiO2 P25. The presented material was prepared in two steps: (i) hydrolysis of titanium (IV) butoxide (TBT) in ethanol solution with simultaneous deposition on graphene oxide (GO) and (ii) calcination of TiO2-GO to form anatase-TiO2 and reduce GO to graphene. The nanomaterial was characterized by transmission electron microscopy (TEM), energy dispersive X-ray spectroscopy (EDX), thermogravimetric analysis (TGA), Fourier-Transformed Infrared spectroscopy and Raman spectroscopy. In the presented photocatalytic process the fluorescence was used to detect (OH)-O-aEuro cent formed on a photo-illuminated n-TiO2-G surface using coumarin which readily reacted with (OH)-O-aEuro cent to produce highly fluorescent 7-hydroxycoumarin.