• 文献标题:   Enhanced photocatalytic hydrogen evolution by combining water soluble graphene with cobalt salts
  • 文献类型:   Article
  • 作  者:   WANG J, FENG K, ZHANG HH, CHEN B, LI ZJ, MENG QY, ZHANG LP, TUNG CH, WU LZ
  • 作者关键词:   cobalt salt, earthabundant catalyst, photocatalysi, photocatalytic hydrogen evolution, waterdispersible sulfonatedgraphene
  • 出版物名称:   BEILSTEIN JOURNAL OF NANOTECHNOLOGY
  • ISSN:   2190-4286
  • 通讯作者地址:   Chinese Acad Sci
  • 被引频次:   7
  • DOI:   10.3762/bjnano.5.128
  • 出版年:   2014

▎ 摘  要

There is tremendous effort put in the pursuit for cheap and efficient catalysts for photocatalytic hydrogen evolution systems. Herein, we report an active catalyst that uses the earth-abundant element cobalt and water-dispersible sulfonated graphene. The photocatalytic hydrogen evolution activity of the catalyst was tested by using triethanolamine (TEOA) as electron donor and eosin Y (EY) as the photosensitizer under LED irradiation at 525 nm. Hydrogen was produced constantly even after 20 h, and the turnover number (TON) reached 148 (H-2/Co) in 4 h with respect to the initial concentration of the added cobalt salts was shown to be 5.6 times larger than that without graphene.