▎ 摘　　要

Polyvinyl chloride (PVC)/graphene and poly(methyl methacrylate) (PMMA)/graphene nanocomposites were made by solution casting technique with graphene weight fractions of 1, 5, 10, 15, and 20%. Multilayer structures of the composites were made by hot compression technique to study their electromagnetic interference shielding effectiveness (EMI SE). Tensile strength, hardness, and storage modulus of the nanocomposites were studied in relation with graphene weight fraction. There has been a substantial increase in the electrical conductivity and EMI SE of the composites with 15-20% filler loading. Differential thermal analysis of the composites shows improved thermal stability with an increase in graphene loading. PMMA/graphene composites have better thermal stability, whereas PVC/graphene composites have superior mechanical properties. About 2mm thick multilayer structures of PMMA/graphene and PVC/graphene composites show a maximum EMI SE of 21dB and 31dB, respectively, in the X band at 20wt % graphene loading. (c) 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 47792.