• 文献标题:   Graphene and cobalt phosphide nanowire composite as an anode material for high performance lithium-ion batteries
  • 文献类型:   Article
  • 作  者:   YANG J, ZHANG Y, SUN CC, LIU HZ, LI LQ, SI WL, HUANG W, YAN QY, DONG XC
  • 作者关键词:   cobalt phosphide, nanowire, anode, lithiumion battery
  • 出版物名称:   NANO RESEARCH
  • ISSN:   1998-0124 EI 1998-0000
  • 通讯作者地址:   Nanjing Tech Univ NanjingTech
  • 被引频次:   54
  • DOI:   10.1007/s12274-015-0941-5
  • 出版年:   2016

▎ 摘  要

The synthesis of a composite of cobalt phosphide nanowires and reduced graphene oxide (denoted CoP/RGO) via a facile hydrothermal method combined with a subsequent annealing step is reported. The resulting composite presents large specific surface area and enhanced conductivity, which can effectively facilitate charge transport and accommodates variations in volume during the lithiation/de-lithiation processes. As a result, the CoP/RGO nanocomposite manifests a high reversible specific capacity of 960 mA center dot h center dot g(-1) over 200 cycles at a current density of 0.2 A center dot g(-1) (297 mA center dot h center dot g(-1) over 10,000 cycles at a current density of 20 A center dot g(-1)) and excellent rate capability (424 mA center dot h center dot g(-1) at a current density of 10 A center dot g(-1)).